Search results for "silica polymorph"
showing 2 items of 2 documents
Experimental Constraints on the Crystallization of Silica Phases in Silicic Magmas
2021
Abstract Low-pressure silica polymorphs, e.g. quartz (Qtz), tridymite (Trd), and cristobalite (Crs), are common in silicic magmas, but the conditions of their formation are still unclear. The stability fields of these polymorphs have been determined in the SiO2, SiO2–H2O, and haplogranite systems, but these simple systems are not directly applicable to silica polymorph crystallization in natural silicic magmas. The present study compiles an experimental database of new and previously-published data documenting the crystallization of silica phases in natural silicic magmas and simple synthetic systems. Silica polymorphs are identified using Raman spectroscopy and their pressure-temperature d…
The formation of silica high temperature polymorphs from quartz: Influence of grain size and mineralising agents
2015
Abstract The formation of high-temperature silica polymorphs in presence of Na and K has been studied at various temperatures and soaking times, starting from quartzes of different grain size, ex situ as well as in situ. The results show that cristobalite and tridymite formation is strongly influenced by the nature and the amount of mineraliser added. In particular, K seems to discriminate more between the two structures, as it produces the largest observed amount of cristobalite. The disappearance of quartz can be controlled by the proper combination of mineraliser/temperature/time, which in turn control the amount and the type of polymorph formed, together with the amount of amorphous mat…